Highly efficient resolution of racemic diethanolamine using chiral camphor-10-sulphonic acid
نویسندگان
چکیده
منابع مشابه
Efficient kinetic resolution of racemic amines using a transaminase in combination with an amino acid oxidase.
A range of enantiomerically pure (R)- and (S)-configured chiral amines has been prepared in excellent e.e. (99%) by combining a transaminase enzyme with an amino acid oxidase and catalytic quantities of pyruvate.
متن کاملSynthesis and Characterization of Poly(o-toluidine) Doped with Camphor Sulphonic Acid
Among the conducting polymers, Polyaniline and its derivatives have been studied extensively in the last decade with improvements in processing having the key role in establishing the intrinsic electrical properties. In the present paper, the camphor sulphonic acid [CSA] doped Poly (o-toluidine) [POT] was prepared using chemical oxidative polymerization method. The prepared CSA doped POT was ch...
متن کاملEffect of solvent polarity on fluoroscence spectra of camphor Sulphonic acid doped Polyaniline
The Camphor sulphonic acid doped polyaniline (CSA-PANi)is synthesized by chemical polymerization method and then characterized by using UV-Visible and FTIR. The surface morphology is studied by SEM and AFM techniques. The degree of crystallinity of PANiis studied by XRD and redox behaviour by cyclic voltametry. Thermal stability of the doped polymer is investigated by TGA and DSC.The fluorescen...
متن کاملExtractive Resolution of Racemic Mandelic Acid through a Bulk Liquid Membrane Containing Binary Chiral Carrier
Um método empregando “bulk liquid membrane” (BLM) e o complexo ácido di(2-etilhexil) fosfórico (D2EHPA) e ácido O,O’-dibenzoil-(2R, 3R)-tartárico (L-(-)-DBTA) foi desenvolvido para a separação por extração do ácido mandélico racêmico (rac MA). Os efeitos de tempo de resolução, concentração de D2EHPA na fase orgânica, concentração de rac MA na fase doadora, velocidade de agitação e temperatura s...
متن کاملEfficient resolution of (±)-trans-2,3-diphenylpiperazine using (1S)-(+)- 10-camphorsulfonic acid and enrichment of enantiomeric purity of non-racemic 2,3-diphenylpiperazine using different achiral acids
Enantiomerically pure (R,R)-(+)-2,3-diphenylpiperazine with 98% ee was obtained by resolution of the corresponding racemic mixture using (1S)-(+)-10-camphorsulfonic acid. The partially resolved enriched sample of (S,S)-(–)-2,3-diphenylpiperazine with 73% ee was purified to obtain samples of 97% ee using different achiral acids via the preparation of either homochiral or heterochiral hydrogen bo...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Arkivoc
سال: 2005
ISSN: 1551-7012
DOI: 10.3998/ark.5550190.0006.b12